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Artistic depiction of water splitting. - © Francesco Ciucci/ midjourney

Under the leadership of BayBatt member Prof. Dr. Francesco Ciucci, a German-Chinese research team has developed a new method for the electrochemical splitting of water. This not only accelerates the production of hydrogen for technology and industry but also makes it more sustainable. The researchers report on their findings in Nature Nanotechnology. 

One of the biggest challenges in electrochemical water splitting is the so-called oxygen evolution reaction (OER), a sluggish reaction in which water molecules are broken down into their individual components—oxygen and hydrogen. The OER can be accelerated by using noble metal catalysts; however, these metals are expensive and scarce, and speeding up the reaction requires additional energy (known as overpotential).

This challenge has been addressed by a research team, consisting of members from various Chinese research institutions and led by Prof. Dr. Francesco Ciucci, Chair of Electrode Design for Electrochemical Energy Systems at the University of Bayreuth. They developed an innovative method for electrochemical water splitting. This approach employs atomically dispersed iridium as reaction accelerators, coupling them with dimethylimidazole and cobalt-iron hydroxide. The key innovation lies in the geometric arrangement of these components, which are configured in an out-of-plane orientation, optimizing performance and efficiency.

This innovative approach significantly increases OER activity and also exhibits an ultra-low overpotential. Additionally, it reduces the use of noble metals, as only individual iridium atoms are used, and it positively impacts the stability of the acceleration reaction.

“Our study represents a significant step forward in developing efficient, cost-effective OER acceleration for sustainable hydrogen production. By overcoming the key challenge of current technology, our results have the potential to drive the global transition towards clean energy solutions,” says Ciucci, the senior author of the study.

To the open access publication "Out-of-plane coordination of iridium single atoms with organic molecules and cobald-iron hydroxies to boost oxygen evolution reaction" (Nature Nanotechnology, 2024).

Read the complete press release by the University of Bayreuth here.